Fu, Liangbing; Xu, Mizhi; Yu, Jiyao; Gutekunst, Will R. published the artcile< Halide-Rebound Polymerization of Twisted Amides>, Reference of 17100-65-1, the main research area is halide rebound polymerization twisted amide.
The first living polymerization of twisted amides is reported, achieved using simple primary alkyl iodides as initiators. Polymerization occurs through a halide-rebound mechanism in which the nucleophilic twisted amide is quaternized and subsequently ring-opened by the iodide counterion. The covalent electrophilic polymerization generates polymers with living chain ends that are both isolable and stable to ambient conditions, enabling the synthesis of block polymers. This presents a new class of polymers for study that possess high glass transition temperatures and robust thermal stability.
Journal of the American Chemical Society published new progress about Chain extension polymerization. 17100-65-1 belongs to class bromides-buliding-blocks, and the molecular formula is C9H9BrO3, Reference of 17100-65-1.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary