Breuers, Christian B. J.; Daniliuc, Constantin G.; Studer, Armido published the artcile< Dearomatizing Cyclization of 2-Iodoindoles by Oxidative NHC Catalysis to Access Spirocyclic Indolenines and Oxindoles Bearing an All Carbon Quaternary Stereocenter>, Related Products of 337536-14-8, the main research area is spirooxindole enantioselective preparation; iodoindolylmethylbenzaldehye NHC catalyst oxidative cyclization.
An intramol. dearomatizing spirocyclization of indoles by oxidative N-heterocyclic carbene catalysis was reported. C2-iodinated indoles are used as substrates in combination with aroyl azolium ions as acceptors, which provides C2-iodinated indolenines containing an all carbon quaternary stereocenter. The products are readily further C2-functionalized and give access to valuable oxindoles by simple hydrolysis in very good overall yields and excellent enantioselectivities.
Organic Letters published new progress about Aralkyl bromides Role: RCT (Reactant), RACT (Reactant or Reagent). 337536-14-8 belongs to class bromides-buliding-blocks, and the molecular formula is C9H8Br2O2, Related Products of 337536-14-8.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary