Organic bromides such as alkyl bromides are used as fumigants in agriculture to control insects. 20469-65-2, formula is C8H9BrO2, Name is 1-Bromo-3,5-dimethoxybenzene. Ethylene bromide is one of the commercially important organic bromides which are the component of leaded gasoline. COA of Formula: C8H9BrO2.
Cauley, Anthony N.;Sezen-Edmonds, Melda;Simmons, Eric M.;Cavallaro, Cullen L. research published 《 Increasing saturation: development of broadly applicable photocatalytic Csp2-Csp3 cross-couplings of alkyl trifluoroborates and (hetero)aryl bromides for array synthesis》, the research content is summarized as follows. Visible light photocatalysis has emerged as an enabling technol. capable of providing access to architecturally complex mols. This article described a systematic investigation of the nickel-mediated photocatalytic cross-coupling of alkyl trifluoroborates and (hetero)aryl bromides aided by high-throughput experimentation (HTE). The results obtained from HTE were utilized to select catalysts, bases and solvents for the production of chem. libraries. Six fourteen-member libraries were generated through couplings with secondary alkyl, primary α-alkoxymethyl, benzyl and secondary α-amino trifluoroborates, demonstrating that the optimized conditions were general, robust and exhibited broad functional group tolerance. The conditions were also successfully adapted for use in a flow reactor, showing the impact micro-scale screening can have in the development of scale-up procedures. These studies enabled the generation of a data-rich reaction guide that provided favorable conditions, as well as alternative conditions that can be used to address issues with substrate solubility or catalyst availability.
COA of Formula: C8H9BrO2, 1-Bromo-3,5-dimethoxybenzene, also known as 1-Bromo-3,5-dimethoxybenzene, is a useful research compound. Its molecular formula is C8H9BrO2 and its molecular weight is 217.06 g/mol. The purity is usually 95%.
1-Bromo-3,5-dimethoxybenzene is used as an intermediate in the synthetic preparation of pharmaceutical inhibitors via cross-coupling reactions.
1-Bromo-3,5-dimethoxybenzene can be synthesized by using 1,3-dimethoxybenzene via iridium-catalyzed arene borylation.
1-Bromo-3,5-dimethoxybenzene (1BDMB) is a synthetic molecule that can be used as an electron acceptor in organic photovoltaic cells. 1BDMB is a salt of the sodium salt of resorcylic acid and 1,3-dibromo-5,5-dimethoxybenzene. It has been shown to have a radical mechanism for the generation of free radicals. The radical mechanism is initiated by light absorption by the ruthenium complex at the center of the molecule which induces photoinduced electron transfer from the ruthenium to 1BDMB. This process results in electron transfer from the donor to an acceptor molecule, such as oxygen or nitrogen. The pharmacokinetic properties of this compound are not well known; however, it has been demonstrated that it can be synthesized through a cross-coupling reaction with other aromatic compounds such as stemofuran., 20469-65-2.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary