Asahara, Teruzo; Seno, Manabu; Tsuchiya, Mitsuru published an article about the compound: Ethyl 3-Ethoxy-2-Propenoate( cas:1001-26-9,SMILESS:O=C(OCC)/C=C/OCC ).SDS of cas: 1001-26-9. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:1001-26-9) through the article.
The Hueckel M.O. method was used to calculate energy levels of vinyl compounds; CH2:CHCN, CH2:CMeCN, Me2C:CHCN, MeCH:CHCN, EtCH:CHCN, CH2:CHCO2Et, Me2C:CHCO2Et, EtOCH:CHCO2Et, trans-BuEtCHCH2O2CCH:CHCO2CH2CHEtBu, MeCH:C(CO2Et)2, PhCH:CHCO2Et, PhCH:CHCN, PhCH:C(CO2Et)2. It is shown that the lower the energies of lowest vacant M.O. (or the higher the electron affinities) the higher the yields of dimers of the vinyl compounds from electrode reactions. Also the higher the π-bond order the lower the yields of dimers.
After consulting a lot of data, we found that this compound(1001-26-9)SDS of cas: 1001-26-9 can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Bromide – Wikipedia,
bromide – Wiktionary