The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 3,4,5-Trichloropyridine, is researched, Molecular C5H2Cl3N, CAS is 33216-52-3, about Gas-phase thermochemistry of chloropyridines, the main research direction is chloropyridine formation enthalpy metal cation affinity.Synthetic Route of C5H2Cl3N.
The gas-phase standard molar enthalpy of formation of 2,3,5-trichloropyridine was derived from the enthalpies of combustion of the crystalline solid measured by rotating-bomb calorimetry and its enthalpy of sublimation obtained by Calvet microcalorimetry at T = 298.15 K. The standard enthalpies of formation for this compound and for the other chloro-substituted pyridines were determined by DFT calculations The exptl. enthalpy of formation of 2,3,5-trichloropyridine is (65.8 ± 2.3) kJ mol-1, in excellent agreement with the B3LYP/6-311+G(2d,2p)//B3LYP/6-31G(d) value. The affinity of pyridine to some metal cations was also calculated at the same DFT level of theory and compared with exptl. data.
In addition to the literature in the link below, there is a lot of literature about this compound(3,4,5-Trichloropyridine)Synthetic Route of C5H2Cl3N, illustrating the importance and wide applicability of this compound(33216-52-3).
Reference:
Bromide – Wikipedia,
bromide – Wiktionary