Name: 1,3-Dimesityl-1H-imidazol-3-ium tetrafluoroborate. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 1,3-Dimesityl-1H-imidazol-3-ium tetrafluoroborate, is researched, Molecular C21H25BF4N2, CAS is 286014-53-7, about Expeditious synthesis of [Au(NHC)(L)]+ (NHC = N-heterocyclic carbene; L = phosphine or NHC) complexes. Author is Gaillard, Sylvain; Nun, Pierrick; Slawin, Alexandra M. Z.; Nolan, Steven P..
Deprotonation of imidazolium or tertiary phosphonium salts by the versatile N-heterocyclic carbene (NHC) gold(I) hydroxide [Au(OH)(IPr)] (IPr = N,N’-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) as precursor permits the expedient synthesis of a series of cationic heteroleptic [Au(NHC)(NHC’)]+ and [Au(NHC)(PR3)]+ complexes. Complete characterization by 1H and 13C NMR spectroscopy and by single-crystal x-ray diffraction was performed in order to discern electronic and structural differences between cationic heteroleptic [Au(NHC)(NHC’)]+ and [Au(NHC)(PR3)]+ congeners.
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