SDS of cas: 286014-53-7. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: 1,3-Dimesityl-1H-imidazol-3-ium tetrafluoroborate, is researched, Molecular C21H25BF4N2, CAS is 286014-53-7, about [Pd(NHC)(allyl)Cl] Complexes: Synthesis and Determination of the NHC Percent Buried Volume (%Vbur) Steric Parameter. Author is Clavier, Herve; Correa, Andrea; Cavallo, Luigi; Escudero-Adan, Eduardo C.; Benet-Buchholz, Jordi; Slawin, Alexandra M. Z.; Nolan, Steven P..
Complexes of Pd bearing NHC ligands (NHC = N-heterocyclic carbene) were synthesized and fully characterized. The [Pd(NHC)(allyl)Cl] series was obtained by simple cleavage of [Pd(allyl)Cl]2 by using either the isolated free NHC or the in situ generated NHC. The NHC ligand sterics were varied by introduction of groups attached to the C4-C5 C atoms of the NHC backbone. Results of the x-ray diffraction study permitted determination of the NHC steric parameters within this series. The NHC backbone induces variations in its percent buried volume (%Vbur) as a function of the N-substituents (© Wiley-VCH Verlag GmbH and Co. KGaA, 69451 Weinheim, Germany, 2009).
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