Synthetic Route of C10H8N2S2. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 4,4-Dipyridyl Disulfide, is researched, Molecular C10H8N2S2, CAS is 2645-22-9, about Crystal structures and magnetic properties of two Co(II) coordination polymers created via in situ ligand synthesis. Author is Zhao, Ying; Dang, Li-Long; Zhai, Zhi-Min; Ma, Lu-Fang; Wang, Li-Ya.
The authors present two new coordination polymers, [Co3(iBuOIPA)3(bps)(H2O)]n (1) and [Co2(iPrIPA)2(bps)]n (2) (bps = 4,4′-bipyridyl sulfide, iBuOIPA = 5-i-butoxyisophthalate, iPrIPA = 5-i-propoxyisophthalate), by the hydrothermal reactions of Co(OAc)2ยท4H2O and 4,4′-bipyridyl disulfide (bpds) with iBuOIPA or iPrIPA, resp. Both crystal structures were determined by single-crystal x-ray diffraction analyses and further characterized by elemental analyses, IR spectra and TG analyses. For 1 and 2, the starting bpds ligands were wholly transformed into bps. Polymer 1 displays a 3-dimensional network constructed from binuclear Co nodes while polymer 2 features a 2-dimensional infinite layer consisting of Co dimers. The existence of electron-donating groups in isophthalate derivatives plays a significant role during the self-assembly of polymers. Also, both 1 and 2 exhibit remarkable magnetic properties, which were studied and discussed in detail, showing a good prospect in magnetic and energy storage devices.
Compound(2645-22-9)Synthetic Route of C10H8N2S2 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(4,4-Dipyridyl Disulfide), if you are interested, you can check out my other related articles.
Reference:
Bromide – Wikipedia,
bromide – Wiktionary