Product Details of 286014-53-7. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 1,3-Dimesityl-1H-imidazol-3-ium tetrafluoroborate, is researched, Molecular C21H25BF4N2, CAS is 286014-53-7, about First telomerisation of piperylene with morpholine using palladium-carbene catalysts. Author is Neubert, Peter; Meier, Ines; Gaide, Tom; Kuhlmann, Rene; Behr, Arno.
Telomerization of common 1,3-dienes like butadiene and isoprene has already been successfully conducted with a huge number of nucleophiles. However, 1,3-pentadiene (piperylene) telomerization with amines has not been reported yet. Here, we present the first telomerization of piperylene with morpholine, providing an atom economic access to unsaturated C10-amines in a single reaction step. Investigations of the reaction conditions such as precursor and ligand screening led to Pd(acac)2/IMes·HCl being the most active catalyst.
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