Application of 286014-53-7. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 1,3-Dimesityl-1H-imidazol-3-ium tetrafluoroborate, is researched, Molecular C21H25BF4N2, CAS is 286014-53-7, about Application of Bulky NHC-Rhodium Complexes in Efficient S-Si and S-S Bond Forming Reactions. Author is Bolt, Malgorzata; Zak, Patrycja.
The efficient and straightforward syntheses of silylthioethers and disulfides are presented. The synthetic methodologies are based on new Rh complexes containing bulky N-heterocyclic carbene (NHC) ligands that turned out to be efficient catalysts in thiol and thiol-silane coupling reactions. These green protocols, which use easily accessible reagents, allow obtaining compounds containing S-Si and S-S bonds in solvent-free conditions. Addnl., preliminary tests on coupling of mono- and octahydro-substituted spherosilicates with selected thiols proved to be very promising and showed that these catalytic systems can be used for the synthesis of a novel class of functionalized silsesquioxane derivatives
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Reference:
Bromide – Wikipedia,
bromide – Wiktionary