Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 286014-53-7, is researched, Molecular C21H25BF4N2, about α-Arylation, α-arylative esterification, or acylation: a stoichiometry-dependent trichotomy in the Pd-catalyzed cross-coupling between aldehydes and aryl bromides, the main research direction is arylaldehyde preparation; arylketone preparation; arylcarboxylate preparation; aldehyde aryl bromide stoichiometry dependent cross coupling palladium catalyst; acylation; arylation; cross-coupling; esterification; palladium.Quality Control of 1,3-Dimesityl-1H-imidazol-3-ium tetrafluoroborate.
A practical protocol for the α-arylation of linear and α-branched aldehydes catalyzed by an air-stable and com. available [(NHC)Pd] complex was developed. The less-common α-arylative esterification of α-branched aldehydes and an unusual acylation of aryl bromides with linear aldehydes by using the very same catalyst was also reported. The reasons behind this mechanistic trichotomy are not yet clear, and it is certainly premature to draw any definitive mechanistic hypotheses.
There is still a lot of research devoted to this compound(SMILES：CC1=C([N+]2=CN(C3=C(C)C=C(C)C=C3C)C=C2)C(C)=CC(C)=C1.F[B-](F)(F)F)Quality Control of 1,3-Dimesityl-1H-imidazol-3-ium tetrafluoroborate, and with the development of science, more effects of this compound(286014-53-7) can be discovered.
Reference:
Bromide – Wikipedia,
bromide – Wiktionary