Little discovery in the laboratory: a new route for 1001-26-9

Here is a brief introduction to this compound(1001-26-9)Electric Literature of C7H12O3, if you want to know about other compounds related to this compound(1001-26-9), you can read my other articles.

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Diethyl acetals of α-formyl esters, published in 1947, which mentions a compound: 1001-26-9, Name is Ethyl 3-Ethoxy-2-Propenoate, Molecular C7H12O3, Electric Literature of C7H12O3.

Zn (100 g., washed with dilute HCl and 3 times with H2O, MeOH, and Me2CO, dried at 100°/20 mm. for 10 min., and used immediately), 25 cc. C6H6, and a crystal of iodine, heated to reflux, and treated dropwise (about 45 min.) with 0.2 mol. of the α-Br ester and 40 cc. (0.24 mol.) HC(OEt)3 in 75 cc. dry C6H6, 25 g. Zn added, and the mixture refluxed 6 hrs., give the di-Et acetals of α-formyl Et esters: propionate, b20 99-102°, 44%; butyrate, b20 112-17°, 51%; isobutyrate, b20 104-7°, 58.5%; valerate, b20 116-20°, 56.5%; caproate, b20 132-6°, 46.5%; hexahydrobenzoate, b20 149-52°, 52.5%. The product from BrCH2CO2Et contains 39% EtOCH:CHCO2Et. NCCHBrCO2Et gives 37% EtOCH:C(CN)CO2Et, m. 49-50°. The acetal esters and 2,4-(O2N)2C6H3NHNH2 in 20% aqueous H2SO4 give 2,4-dinitrophenylhydrazones of α-formyl Et esters: propionate, m. 110-11.5°; butyrate, m. 106-8°; isobutyrate, m. 104.5-5°; valerate, m. 121-3°; caproate, m. 86.5-8°; hexahydrobenzoate, m. 150-2°. Hexahydrobenzaldehyde 2,4-dinitrophenylhydrazone, yellow m. 168-9°.

Here is a brief introduction to this compound(1001-26-9)Electric Literature of C7H12O3, if you want to know about other compounds related to this compound(1001-26-9), you can read my other articles.

Reference:
Bromide – Wikipedia,
bromide – Wiktionary