Related Products of 7314-86-5, In the next few decades, the world population will flourish. As the population grows rapidly and people all over the world use more and more resources, all industries must consider their environmental impact. 7314-86-5, name is 1,3,5,7-Tetrabromoadamantane belongs to bromides-buliding-blocks compound, it is a common compound, a new synthetic route is introduced below.
1,3-dibromobenzene (70 mL) was added to a mixture of 1,3,5,7-tetrabromoadamantane (5.0 g, 11.1 mmol) and AlCl3 powder (4.0 g,30.0 mmol), at 0 C. The mixture was then stirred at ambient temperaturefor 36 h. After quenching the reaction by adding ice water, theorganic layer was diluted with chloroform and filtered. The filtrate waswashed with deionised water and brine and then dried over magnesiumsulfate. After evaporation to remove volatiles, 1,3,5,7-tetrakis(1,3-bibromophenyl)adamantane was obtained as a white solid from thecrystallization in chloroform (9.6 g, 81% yield). 1H NMR (DMSO-d6,400 MHz): delta (ppm) 7.80 (s, 8H), 7.69 (s, 4H), 2.05 (s, 12H); 13C NMR(CDCl3-d3, 400 MHz): delta (ppm) 150.7, 131.5, 126.2, 122.4, 45.3, 38.3.Anal. Calcd for C34H24Br8: C, 38.10; H, 2.26; Found: C, 38.11; H, 2.21.
In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles, 1,3,5,7-Tetrabromoadamantane, other downstream synthetic routes, hurry up and to see.
Reference:
Article; Li, Xiong; Guo, Jianwei; Tong, Rui; Topham, Paul D.; Wang, Jiawei; Reactive and functional polymers; vol. 130; (2018); p. 126 – 132;,
Bromide – Wikipedia,
bromide – Wiktionary