Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 768-90-1, Name is 1-Bromoadamantane, SMILES is BrC12CC3CC(C2)CC(C3)C1, in an article , author is Saghyan, Ashot S., once mentioned of 768-90-1, Computed Properties of C10H15Br.
Synthesis of Enantiomerically Enriched Alkynylaryl-Substituted alpha-Amino Acids through Sonogashira Reactions
Various enantiomerically enriched non-proteinogenic (S)-alpha-amino acids were obtained in high chemical and optical yields through Sonogashira cross-coupling reactions and Glaser couplings. The Schiff base Ni(II)complexes of the chiral auxiliary (S)-BPB (BPB = N-benzyl proline benzophenone) and an amino acid containing an aryl bromide moiety in the alpha-position were synthesized and subsequently used in Sonogashira coupling reactions. The obtained Ni(II) complexes were hydrolyzed with aqueous HCl and novel amino acids, containing an alkynylaryl moiety, were isolated in good yields and with high enantiomeric excess (>99% ee). The chiral auxiliary (S)-BPB can be recycled and reused for the synthesis of the starting Ni(II) complex.
But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! 768-90-1, you can contact me at any time and look forward to more communication. Computed Properties of C10H15Br.