Related Products of 506-26-3, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 506-26-3, Name is (6Z,9Z,12Z)-Octadeca-6,9,12-trienoic acid, SMILES is CCCCC/C=CC/C=CC/C=CCCCCC(O)=O, belongs to bromides-buliding-blocks compound. In a article, author is Wang, Chen, introduce new discover of the category.
Lewis acid/base pair as a catalytic system for alpha-stereoselective synthesis of 2-deoxyglycosides through the addition of alcohols to glycals
This report describes the alpha-stereoselective addition of alcohols to glycals promoted by a cooperative Lewis acid/base pair catalytic system composed of B(C6F5)(3) and tetrabutylammonium bromide (TBAB), which provides access to 2-deoxylglycosides in high yields. A mechanistic investigation supported by NMR analysis highlights the possible involvement of nucleophilic addition through boron-induced activation of alcohols under the assistance of TBAB. The protocol discussed here features the high stereoselectivity, mild reaction conditions, inexpensive and stable catalysts, and a broad substrate scopes. (C) 2020 Elsevier Ltd. All rights reserved.
Related Products of 506-26-3, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. I hope my blog about 506-26-3 is helpful to your research.