In an article, author is Ling, Bo, once mentioned the application of 3958-60-9, Name: 1-(Bromomethyl)-2-nitrobenzene, Name is 1-(Bromomethyl)-2-nitrobenzene, molecular formula is C7H6BrNO2, molecular weight is 216.032, MDL number is MFCD00007184, category is bromides-buliding-blocks. Now introduce a scientific discovery about this category.
Cooperative N-Heterocyclic Carbene/Palladium-Catalyzed Umpolung 1,4-Addition of Vinyl Bromides to Enals
A highly stereoselective umpolung 1,4-addition of vinyl bromides to enals is enabled by NHC/palladium cooperative catalysis, generating various valuable.,d-unsaturated carbonyl derivatives in excellent yields (up to 90%). A detailed mechanism investigation indicates the NHC act as both organocatalyst and ligand for palladium during this system.
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