In an article, author is Sharghi, Hashem, once mentioned the application of 98475-07-1, SDS of cas: 98475-07-1, Name is Methyl 2-(bromomethyl)-3-nitrobenzoate, molecular formula is C9H8BrNO4, molecular weight is 274.07, MDL number is MFCD04114315, category is bromides-buliding-blocks. Now introduce a scientific discovery about this category.
N-Arylation of Nitrogen-Containing Heterocycles with Cu(II) Complex of 4-(2,2 ‘:6 ‘,2 ”-Terpyridin-4 ‘-yl)toluene as a Versatile and Efficient Catalyst
Copper(II) complex of 4-(2,2′:6′,2 ”-terpyridin-4’-yl)toluene(ttpy) was found to be a profitable catalyst for the N-arylation of a variety of nitrogen-containing heterocycles, such as some kinds of azoles and a secondary aliphatic amine, with aryl halides (iodides, bromides, and chlorides) under moderate conditions. A variety of functionalized aryl halides were tolerated in good to excellent yields by this air stable and low cost Cu(II)-based catalytic system. Phenyl boronic acid was also used as an alternative to aryl halides to supply aryl moiety.
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