2695-47-8, Name is 6-Bromo-1-hexene, molecular formula is C6H11Br, belongs to bromides-buliding-blocks compound, is a common compound. In a patnet, author is Monroe, Jeffrey C., once mentioned the new application about 2695-47-8, Category: bromides-buliding-blocks.
Effects of deuteration on the structure and magnetic properties of bis-quinolinium tetrabromidocuprate(II) dihydrate
The partially [d(6), 2] and fully [d(20), 3] deuterated analogues of (QuinH)(2)CuBr4 center dot 2H(2)O (d(0), 1) were prepared and their crystal structures were determined [Quin = quinoline]. In both compounds, there is a clear disorder in the positions of the bromide ions which was resolved. This led to a reexamination of the structure of the parent, fully protonated compound (1) where a small percentage of previously unrecognized disorder was also observed and the structure rerefined. Variable temperature magnetization measurements over the range 1.8-310 K indicate that all three materials behave as magnetically well-isolated layers that can be evaluated using the 2D-quantum Heisenberg antiferromagnetic model. Final fitting results for the partially (J = -5.96(5) K) and fully (J = -5.77(2) K) deuterated compounds indicate slightly weaker exchange compared to the protonated compound (J = -6.17(3) K), likely as a result of the increased disorder in the deuterated phases.
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