Synthetic Route of 54962-75-3, Catalysts allow a reaction to proceed via a pathway that has a lower activation energy than the uncatalyzed reaction. 54962-75-3, Name is 3-Bromo-5-(trifluoromethyl)aniline, SMILES is C1=C(C(F)(F)F)C=C(Br)C=C1N, belongs to bromides-buliding-blocks compound. In a article, author is Ji, Xiaochen, introduce new discover of the category.
LiBr-promoted photoredox neutral Minisci hydroxyalkylations of quinolines with aldehydes
Photoredox-neutral hydroxyalkylations of quinolines with aldehydes, induced by sustainable visible light under mild conditions, are described. Non-toxic and inexpensive LiBr is found to be the key for the success of the atom-economical Minisci method. Combined with a highly oxidative photocatalyst and visible light irradiation, the bromide additive mediates the H abstraction/acyl radical formation directly from aldehydes. The present mild photoredox neutral protocol provides an important alternative, especially for the challenging Minisci hydroalkylations, as well as a promising approach for atom-economical Minisci reactions with broader N-heterocycle spectra.
Synthetic Route of 54962-75-3, Each elementary reaction can be described in terms of its molecularity, the number of molecules that collide in that step. The slowest step in a reaction mechanism is the rate-determining step.you can also check out more blogs about 54962-75-3.